Authors are requested to submit articles directly to Online Manuscript Submission System of respective journal.Internationally renowned scientists describe their own research in the wider context of the field.These journal publishes recent developments in physical chemistry, chemical physics and theoretical chemistry.It is an online manuscript Submission, Review and Tracking system.
The Editorial Board Members of the Journal performs the review processing. Authors may submit manuscripts and track their progress through the system. If X is the total number of articles published in 2014 and 2015, and Y is the number of times these articles were cited in indexed journals during 2016 then, impact factor YX. As such it is aimed at scientists working in this field not only in chemistry itself but also in biochemistry pharmaceutical chemistry materials and polymer science and in other areas of research in which the approaches used in physical organic chemistry are now applied. JPOC is published monthly as a classical journal presenting all material that can be published in printed form. Additional electronic material-color images dynamic chemical structures videos simulations-and extensive supplementary material are published in EPOC. The Journal of Physical Organic Chemistry will devote particular attention to the following fields: Organic chemistry; Bio-organic chemistry; Organometallic chemistry; Theoretical chemistry; Catalytic chemistry; Photochemistry; Supramolecular chemistry. Among the topics covered within the fields will be: Reaction mechanisms; Reactive intermediates; Combinational stategies; Novel structures; Spectroscopy; Chemistry at interfaces; Stereochemistry; Conformational analysis; Quantum chemical studies; Structure-reactivity relationships; Solvent isotope and solid-state effects; Long-lived charged sextet or open-shell species; Magnetic non-linear optical and conducting molecules; Molecular recognition. RG Journal Impact: 1.03 This value is calculated using ResearchGate data and is based on average citation counts from work published in this journal. Isaacs Mark Coulson The Maillard reaction between tryptophan and glucose or xylose was studied as a function of pressure. Using model reactions, volumes of activation for the formation of the intermediate imine and the Amadori rearrangement and for the decomposition of the aminoketose were measured as 14, 8 and 17 cm3mol1, respectively. Pressure therefore accelerates the initial reactions but retards the formation of the final heterocyclic products and melanoidins. View Expand abstract Activation of double and triple bonds in C6 unsaturated hydrocarbons by the Ru(001) surface: An overview Article Jul 2008 Ana Garcia Ricardo Brito Barros Laura M. Ilharco The decomposition patterns of hexene and hexyne isomers on clean Ru(001), under ultra-high vacuum, are overviewed and correlated with functionality and isomerism. The key surface intermediates and products were identified by reflection absorption infrared spectroscopy (RAIRS). The results evidence the relevant role of the unsaturation position over its nature. The effects of steric hindrance and geometrical isomerism are apparent only in the inhibition of some decomposition pathways. The RAIRS data show that 1-hexene chemisorbs at low temperature (90 K) and coverage as a di- complex, whereas 1-hexyne forms a di- complex. By thermal activation, both these species dehydrogenate (in C1), yielding hexylidyne 3-1-C(CH2)4CH3, which further decomposes (at 280290 K) into surface metallocycles, Ru3C(CH2)4CH2-Ru and Ru3C(CH2)4CRu3. Eventually, at 300 K, complete CC bond breaking occurs, yielding just adsorbed methylidyne 3-1-CH. The hexene and hexyne isomers with the unsaturation between secondary carbons may follow two surface-assisted decomposition mechanisms. At low temperatures, they adsorb as the corresponding alkyne di- complex, which implies a rehybridization of the sp2 (or sp) carbons with reduction of the bond order, plus, for alkenes, dehydrogenation at the same carbons. These complexes decompose by breaking the CC bonds adjacent to the surface anchors: C1C2 and C3C4 in the case of the 2-isomer, yielding methylidyne, ethyne di- complex 3-2-CHCH and propylidyne 3-1-CCH2CH3, and C2C3 and C4C5 in the 3-isomer, with the formation of the ethyne di- complex and ethylidyne 3-1-CCH3. The second decomposition path occurs upon direct adsorption at the reaction temperatures. It involves the scission of the multiple bond, with the formation of shorter chain alkylidynes: propylidyne (for 3-hexyne and Z-3-hexene), ethylidyne and butylidyne 3-1-C(CH2)2CH3 (for 2-hexyne). The reactivity of Z-2-hexene revealed to be different, since no evidence was found for the second decomposition path. This was ascribed to a reduced accessibility of the double bond to the surface, due to a steric hindrance effect of the alkyl chain. The influence of geometrical isomerism was particularly clear in the decomposition of E-3-hexene, which has a remarkable stability. View Expand abstract Kinetics of the hydrolysis of cyclic Nsubstituted sulfamides: 4amino2cyclohexyl and 4amino2phenethyl2,3dihydro3oxo1,2,5thiadiazole 1,1dioxides Article Dec 1998 M. F. Rozas Esther Lea Svartman Mara Virginia Mirfico Enrique Julio Vasini The hydrolysis reactions of 4-amino-2-phenethyl- and 4-amino-2-cyclohexyl-2,3-dihydro-3-oxo-1,2,5-thiadiazole 1,1-dioxide (Ia and Ib) were investigated in the range 2473 C in buffered aqueous solutions.
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